Development of graphene oxide as a protective coating on biodegradable magnesium implant
Mohamed salah Atallah
, Akila Khlifi
, Kaouther Khlifi
, Marie Jonas Sima Nkele
, Najoua Barhoumi
, Masoud Atapour
Abstract: Recently, magnesium alloys including AZ31 have attracted attention in bone regeneration applications such as temporary orthopedic implants due to their high biocompatibility and biodegradability. In the present work, graphene oxide was synthesized by the Hummer process and deposited on magnesium alloy AZ31 by spin coating. The effect of graphene oxide on the surface morphology was defined by Scanning Electron Microscopy and Fourier Transformation Infrared Spectroscopy. Also, the adhesion of graphene oxide to magnesium alloy substrates was evaluated using a scratch tester. Furthermore, the friction and wear behavior of the coatings were tested using multiple scratches. The results show that the graphene oxide coating was successfully deposited on magnesium alloy, and its good adhesion and high wear resistance provide potential for future orthopedic applications.
Series on Biomechanics, Vol.37, No.4 (2023), 85-92
Keywords: graphene oxide (GO); Magnesium alloys; spin coating; wear resistance
References: (click to open/close) | [1] Zhang, ZQ., Yang, YX., Li, JA., Zeng, RC., Guan, SK., 2021. Advances in coatings on magnesium alloys for cardiovascular stents – A review. Bioactive Materials 12, 4729–4757. [2] Sarian, MN., Iqbal, N., Sotoudehbagha, P., Razavi, M., Ahmed, QU., Sukotjo, Q., Hermawan, H., (2022). Potential bioactive coating system for high-performance absorbable magnesium bone implants, Bioactive Materials 12, 42-63. [3] Chandra G, Pandey, A., 2020. A Preparation Strategies for Mg-alloys for Biodegradable Orthopedic Implants and Other Biomedical Applications: A Review. IRBM 43, 229-249. [4] Vennimalai Rajan, A., Mathalai Sundaram, C., Vembathu Rajesh, A., 2019. Mechanical and morphological investigation of bio-degradable magnesium AZ31 alloy for an orthopaedic application. Materials Today: Proceedings 21, 272-277. [5] Poinern, GEJ., Brundavanam, S., Fawcett, D., 2012. Biomedical magnesium alloys: a review of material properties, surface modifications and potential as a biodegradable orthopaedic implant. American Journal of Biomedical Eng 6, 218–240. [6] Xiong, Y., Hu, X., Song, R., 2017. Characteristics of CeO2/ZrO2-HA composite coating on ZK60 magnesium alloy. Journal of Materials Research 32, 1073–1082. [7] Bogya, ES., Károly, Z., Barabás, R., 2015. Atmospheric plasma sprayed silica–hydroxyapatite coatings on magnesium alloy substrates. Ceramics International 41, 6005–6012. [8] Ho, YH., Joshi, SS., Wu, TC., Hung, CM., Ho, NJ., Dahotre, NB., 2020. In-Vitro Bio-Corrosion Behavior of Friction Stir Additively Manufactured AZ31B Magnesium Alloy-Hydroxyapatite Composites. Materials Science and Engineering: C 109, 110632. [9] Bansal, P., Singh, G., Sidhu, HS., 2020. Investigation of surface properties and corrosion behavior of plasma sprayed HA/ZnO coatings prepared on AZ31 Mg alloy. Surface and Coatings Technology, 401, 126241. [10] Long, Y., Wu, L., Pan, F., Zhang, Z., Yang, M., Tang, A., Atrens, A., 2019. A Graphene Spin Coatings for Cost-Effective Corrosion Protection for the Magnesium Alloy AZ31. Journal of Nanoscience and Nanotechnology 19, 105–111. [11] Liu, Y., Ding, J., Wang, QQ., Wen, M.L., Tang, TT., Liu, Y., Yuan, R.., Li, YF., An, MW., 2021. Research progress on the biomedical uses of graphene and its derivatives. New Carbon Materials 36, 779-793. [12] Xu, Y., Bai, H., Lu, G., Li, C., Shi, G., 2008. Flexible Graphene Films via the Filtration of Water-Soluble Noncovalent Functionalized Graphene Sheets. Journal of the American Chemical Society 130, 5856–5857. [13] Hummers, WS., Offeman, R.E., 1958. Preparation of Graphitic Oxid. Journal of the American Chemical Society 80, 1339–1339. [14] Suk, JW., Piner, RD., An, J., Ruoff, RS., 2010. Mechanical Properties of Monolayer Graphene Oxide. ACS Nano 4, 6557–6564. [15] Kucukosman, R., Sukuroglu, EE., Totik, Y., Sukuroglu, S., 2020. Effects of graphene oxide addition on wear behaviour of composite coatings fabricated by plasma electrolytic oxidation (PEO) on AZ91 magnesium alloy. Journal of Adhesion Science and Technology 35, 242-255. [16] Tong, LB., Zhang, JB., Xu, C., Wang, X., Song, SY., Jiang, ZH., Zhang, HJ., 2016. Enhanced corrosion and wear resistances by graphene oxide coating on the surface of Mg-Zn-Ca alloy. Carbon 109, 340–351. [17] Berman, D., Erdemir, A., Sumant, AV., 2014. Graphene: a new emerging lubricant. Mater Today 17, 31–42. [18] Khlifi, K., Atallah, MS., Cherif, I., Karkouch, I., Barhoumi, N., Attia-Essaies, S., 2023. Synthesis of ZnO nanoparticles and study of their influence on the mechanical properties and antibacterial activity of PMMA/ZnO composite for orthotic devices. Surfaces and Interfaces 41, 103279. [19] Barhoumi, N., Khlifi, K., Maazouz, A., Lamnawar, K., 2022. Fluorinated ethylene propylene coatings deposited by a spray process: mechanical properties, scratch and wear behavior. Polymers 14, 347. [20] Barhoumi, N., Ghanem, A., Koudhai, M., Khlifi, K., Terras, MA.,2022. Improving the mechanical, wear and anti-corrosion performance of polyester coating on structural steel by graphite addition, J. Express Polymer Letters 16, 476-487. [21] Barhoumi, N., Khlifi, K., Attia-Essaies, S., 2023.Mechanical and bioactive properties of PVD TiO2 coating modified PEEK for biomedical applications, Journal of the Mechanical Behavior of Biomedical Materials. 144, 105935. [22] Ghanem, A., Atallah, MS., Khlifi, K., Barhoumi, N., Terres, MA., 2022. Investigation of friction and wear resistance of carbonitrided AISI 4130 steels using single and multi-pass scratch technique. Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science 236, 203-210.
|
|
| Date published: 2023-11-28
(Price of one pdf file: 39.00 BGN/20.00 EUR)