Microstructure, mechanical and wear properties of Poly(methyl-methacrylate) biopolymer modified with synthesis manganese and nickel nano-oxides
Chokri Ben Aissa
, Najoua Barhoumi
, Saïda FatmaChérif
, Kaouther Khlifi
, Abd El Hedi Gabsi
Резюме: Objective: This work attempts to develop a multifunctional Poly(Methyl-Methacrylate) biopolymer (PMMA)-based composite material with higher antimicrobial activity and improved mechanical properties. Materials and methods: The synthesis process consisted of incorporating 2 wt% of synthetic manganese and nickel nanooxides into a PMMA matrix. The prepared composites were characterized through several tests to determine the effect of the addition of both fillers on the structural and mechanical properties of the PMMA material. Results: It was found that the nanoparticles were evenly distributed in the matrix, resulting in an enhanced effect. The incorporation of NiO and Mn2O3 into PMMA can increase the hardness value by a factor of 21 and 13 respectively. They also reduced the coefficient of friction of PMMA from 0.6 to 0.2 and 0.15, respectively. In addition, tribological study show that the addition of manganese and nickel oxides increases the wear resistance of modified PMMA. Conclusion: Finally, this work shows that the addition of nanoparticles, especially NiO, significantly improves the mechanical properties and tribological behavior of the PMMA biopolymer.
Series on Biomechanics, Vol.37, No.4 (2023), 54-59
Ключови думи: composite; hardness; microstructure; nano-oxides; PMMA; wear
Литература: (click to open/close) | [1] Williams H. P., F. Frcophth, 2001. Sir Harold Ridley’s vision, British Journal of Ophthalmology, 85, 9, 1022–1023. [2] Shahmohammadi M., Nagay B. E., Barão V. A. R., Sukotjo C., Jursich G., Takoudis C. G., 2022. Atomic layer deposition of TiO2, ZrO2 and TiO2/ZrO2 mixed oxide nanofilms on PMMA for enhanced biomaterial functionalization, Appl Surf Sci, 578. 151891. [3] Lyutakov O., Goncharova I., Rimpelova S., Kolarova K., Svanda J., Svorcik V., 2015. Silver release and antimicrobial properties of PMMA films doped with silver ions, nano-particles and complexes, Materials Science and Engineering, C, 49. 534–540. [4] Zafar, M. S., 2020. Prosthodontic Applications of Polymethyl Methacrylate (PMMA): An Update, Polymers 2020, 12, 10. [5] Khlifi, Kaouther, et al., 2023. Synthesis of ZnO nanoparticles and study of their influence on the mechanical properties and antibacterial activity of PMMA/ZnO composite for orthotic devices. Surfaces and Interfaces, 41. [6] Youssef, Ahmed, et al., 2019. Preparation and characterization of PMMA nanocomposites based on ZnO-NPs for antibacterial packaging applications. Proceedings of the 5th World Congress on New Technologies (NewTech'19) Lisbon, Portugal. ICNFA. 105. [7] Yamabe J., Nishimura S., 2009. Influence of fillers on hydrogen penetration properties and blister fracture of rubber composites for O-ring exposed to high-pressure hydrogen gas, Int J Hydrogen Energy, 34, 4, 1977–1989. [8] Hammani, Salim, Ahmed Barhoum, Mikhael Bechelany, 2018. Fabrication of PMMA/ZnO nanocomposite: effect of high nanoparticles loading on the optical and thermal properties. Journal of Materials Science 53. [9] Guo, B. C., Chen F., Chen, W. W., Lei Y. D., Jia D. M., 2010. Reinforcement of nitrile rubber by in situ formed zinc disorbate, Express Polym Lett, 4, 9. 529–538. [10] Barhoumi, Najoua, Kaouther Khlifi, and Sameh Attia-Essaies, 2023. Mechanical and bioactive properties of PVD TiO2 coating modified PEEK for biomedical applications. Journal of the Mechanical Behavior of Biomedical Materials 144. [11] Saod, W. M., Hamid,L L., Alaallah N. J., Ramizy A., 2022. Biosynthesis and antibacterial activity of manganese oxide nanoparticles prepared by green tea extract, Biotechnology Reports, 34, p.e 00729. [12] Behera, N., et al.,2019. Oxidative stress generated at nickel oxide nanoparticle interface results in bacterial membrane damage leading to cell death, RSC Adv, 9, 43. 24888–24894. [13] Barhoumi N., Ghanem A., Koudhai M., Khlifi K., Terras M. A., 2022. Improving the mechanical, wear and anti-corrosion performance of polyester coating on structural steel by graphite addition, Express Polym Lett, 16, 5. 476–487.
|
|
| Дата на публикуване: 2023-11-28
(Price of one pdf file: 39.00 BGN/20.00 EUR)